CHEM-542 THERMODYNAMICS-II, PHASE EQUILIBRIUM & RADIO CHEM-

Thermodynamics II: Spontaneous processes, cannot cycle, staement of second law, concept of entropy, combined form of the first and second law of Thermodynamics, enthalpy and entropy, Thermodynamics equation of state (energy as a function of V, & T, enthalpy as a function of T & P), entropy in isolated system, variation of entropy with temperature & volume, variation of entropy with temperature and pressure, Entropy change in chemical reaction, Helmholtz and Gibbs free energies, Properties of Gibbs-Helmholtz equation.

Phase Rule: Phase, component and degree of freedom, Phase rule and its application to one component (water and Sulpher), biocomponent system (Ag + Pb), KI + H2O).

Radiochemistry: Definition and measurement of radioactivity, rate of atomic disintegration radioactive equilibrium, theory of radioactivity artificial transmutation of elements, induced radioactivity and nuclear energy, nuclear fission and fission, radioactive isotopes.