CHEM-562 PHOTOCHEMISTRY & ADVANCED WAVE MECHANICS-

Photochemistry: Photochemistry and thermal reactions, Chain reaction, free radical chains, thermal decomposition of acetaldehyde and ethane, Lambert and Beer’s law, Grothus Draper’s law, Elinstin law of decomposition of hydrogen-iodide, hydrogen-bromine etc, Fluoescence, Photosensitization, Phosphorescence Chemiluminescence.

Thermodynamics: Law of mass action (thermodynamic derivation, reaction isotherm and Vant Hoff equation (influence of temperature on equilibrium constant), Partial molar quantities, Chemical potential, Gibbs Duhem equation, Effect of temperature and pressure on chemical potential, Chemical potential of real gases and fugacity, Thermodynamic treatment of colligative properties (lowering vapour pressure, elevation of boiling point, depression of freezing point, osmotic pressure).

Atomic Structure & Wave Mechanic: Bohr’s theory, Sommerfeld’s model, dual nature of electron, De Broglies concept of the dual nature of the electron, de-Broglies equation, experimental verfication (Davisson and Germer’s experiment), Heisenbergs uncertainity principle and its derivation-Schrocdinger wave equation (derivation), Schrodinger equation with respect to time, Eigen values and functions, Operators (Addition and Substraction of operators, Multiplication, Linear, Hamiltonian, Hermitian), Postuates of Quantum mechanism, free particle, particles in potential barrier, Particle in one dimensional box, Particle in 3 dimentional box, Simple Harmonic Oscillator, Hydrogen Atom.